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Index >> Bacterial Photosynthesis >> Structure of Chlorophyll

Structure of Chlorophyll

Structure of Chlorophyll - The emperical formula of chlorophyll a is C55H72O5N4Mg. Chlorophyll a is a blue-green microcrystalline solid, consisting of a 'head' and a 'tail'.

The head consists of a porphyrin ring or tetrapyrrole nucleus, from which extends a tail made up of a 20-carbon grouping called the phytol.

The porphyrins are complex carbon nitrogen molecules that usually surround a metal. In chlorophyll the porphyrin, surrounds a magnesium ion while in haemoglobin it surrounds an iron, ion.

The cytochromes of the electron transport system also have porphyrin rings. The basic unit of the porphyrin ring is the porphobilinogen molecule. Four such pyrroles make up units of the tetrapyrrole structure.

Phytol is a long straight chain alcohol containing a double bond. It may be regarded as a hydrogenated carotene (vitamin A). Its formula is C20H39.

Chlorophyll b has the emperical formula C55H70O6N4Mg, It is a green black microcrystalline solid. It differs from chlorophyll a in having an aldehyde (CHO) group attached to carbon atom 3, instead of a methyl (CHs) group.

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