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Index >> Biodegradation of Pesticides and Pollutants >> Aldrin Dieldrin Heptachlor Endosulfan Chlordane

Aldrin Dieldrin Heptachlor Endosulfan Chlordane

Aldrin, Dieldrin, Heptachlor, Endosulfan, Chlordane
This group of organochlorine insecticides is generally known as dieneorganochlorine insecticides or cyclodienes-cyclo means cyclic or ring structures and diene means containing two double bonds. They have three dimensional structures and exist as stereoisomers whose atoms differ in their spatiallocation and structure, with one and frequently two methanobridges, one located in the chlorinated ring (marked 2 in the diagram below) and the other in the unchlorinated ring (marked 1 in the diagram below).

These methanobridges are bent inside (endo) or outside (exo) of the cage structure as exemplified by aldrin which is converted to dielderin by Trichoderma, Fusarium, Penicillium and Pseudomonas without loss of insecticidal property.

Aldrin

Dieldrin

Aldrin [1,2,3,4,10,10-hexachloro 1,4,4a,5,8,8a-hexahydro-1, 4-endo-exo-5, 8-dimethanophthalene]

Dieldrin [1,2,3,4,10,10-hexachloro 6,7-epoxy-1,4,4a,5,6,7,8,8a-octahydro-1,4-endo-exo-5,8-dimethoanonaphthalene


The names aldrin and dieldrin go after the Nobel Prize winning German chemists Otto P.H. Diels and Kurt Alder. These insecticides are persistent and stable in soil and are very effective against termites.

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