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Index >> Nitrification and Denitrification >> Controlled Release Fertilizers and Nitrification Inhibitors

Controlled Release Fertilizers and Nitrification Inhibitors

Controlled Release Fertilizers and Nitrification Inhibitors

The release of nutrient from nitrogenous fertilizers can be controlled by the use of 'controlled release fertilzers' which have been formulated and used successfully in Japan and U.S.A. Examples of this kind of new fer­tilizers are ureaform, isobutyledene diurea, crotonilidene diurea and sulphurcoated urea. They are sparingly soluble in water and by virtue of this property can regulate the release of nitrogen from fertilizers. Under experimental conditions in northern India, these fertilizers have been tried in rice fields and found to get mineralized at a slower rate than ordinary urea and also provide residual nitrogen for augmenting the yield of sub­sequent wheat crop.

The prohibitive cost of these materials, at present, prevents their immediate utility on the farm.
Some of the chemicals which are known to act as nitrification inhibitors are produced in U.S.A. and Japan, and are expensive. These chemicals are substituted pyridines, pyrimidines, acetanilides, anilines and isothiocyanates. The two major compounds which have been commercially produced by the Dow Chemical Co., U.S.A. and the Toyo Koatsu Co., of Japan are 2-chloro-6-(trichloromethyl)-pyridine, commonly known as N­serve and 2-amino-4-chloro-6-methyl pyridine commonly known as AM. At level of 1.0 ppm, N-serve inhibits the growth of Nitrosomonas europea and N. agiUs. Oxidation of ammonium by fresh cell suspensions of Nitrosomonas was completely suppressed at 1.p ppm of the chemical.
In experiments done at the Indian Agricultural Research Institute, it was seen that N-serve and AM effectively retarded the nitrification of ammonium sulphate and reduced the losses of nitrogen from soil under water-logged conditions. Increase in yields of rice due to application of ammonium sul­phate in the presence of N-serve has also been observed . The beneficial effect of N-serve has also b!!en recorded in experiments carried out by independent workers with graJses, tomato and spinach.

Grain yield (q/ha) of wheat as influenced by residual N from rice and rates of N applied to wheat. (from Prasad, 1975)

Source of N applied (10 kg/ha) to rice

 

Rates of N (kg/ha) applied to wheat

0

50

100

Urea

9.2

31.2

35.9

Sulphur-coated urea (TVA)

14.9

38.2

44.2

Lac-coated urea

12.7

34.8

41.9

Neem cake treated urea

14.9

38.8

50.7

Sulphathiazole treated urea

15.4

40.0

49.6

Coalter treated urea

13.5

31.4

43.9

Control (no nitrogen)

3.9

17.0

33.0

C.D. 5%

-

1.7

-

--lq = 100 kg

 

Table 36 Influence of nitrification inhibitor treatment and variety on grain yield and nitrogen uptake by rice (from Prasad, 1974)

Treatment (averaged over 40, 80 and 120 kg N/ha)

 

 

1966

 

1967

Taichung Native-1

NP 130

Taichung Native-1

NP 130

Ammonium sulphate

44.1

41.3

63.4

48.1

Ammonium sulphate + ‘N-Serve’

48.4

45.1

63.7

50.8

Ammonium sulphate + ‘AM’

50.1

43.9

67.7

49.3

C.D.5%

2.5

2.4

 

Nitrogen uptake (kg N/ha)

Ammonium sulphate

87

81

103

103

Ammonium sulphate + ‘N-Serve’

100

89

128

111

Ammonium sulphate + ‘AM’

104

89

131

110

C.D.5%

6

3

The seeds of neem tree (Azadirachta indica) contain certain lipid asso­ciates which act as nitrification inhibitors and thereby increase the efficiency of urea fertilizer. Increased yields due to the application of neem cake with urea fertilizers have been recorded and further work in this direction may open up the possibility of providing suitable and inexpensive substitute to N-serve and AM.

  • Losses of Nitrogen by Non Biological Ways
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