Copper is precipitated by H2S producing soil microorganisms. Apart from Desulfovibrio desulfuricans which reduces sulphate, bacteria such as Clostridium lentoputrescens. Proteus vulgaris and Escherichia coli may produce H2S from sulphur containing amino compounds such as cystine, methionine and glutathione under anaerobic conditions.
That H2S producing bacteria are involved in the precipitation of copper rendering the element insoluble has been clearly demonstrated in experiments with barley and oats. In such experiments, the precipitate of copper formed by D. desulfuricans and E. coli were fed to copper-deficient plants and the plants showed no recovery. A second set of plants treated with copper sulphate along with sterilized bacterial medium recovered from copper-deficiency symptoms. Apparently, in the later case, there was no bacteria-mediated precipitation of copper.
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