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Adsorption

Adsorption - Adsorption is the accumulation of molecules from a substance dissolved in a solvent onto the surface of an adsorbent particle (Tebbut, 1992). Adsorption techniques are used to remove soluble organic from drinking waters and wastewaters.

Tiny concentrations of both natural and synthetic organic compounds produce serious taste and odor problems in water. Moreover, long term exposure to these organics may lead to potential health hazards. Thus the needs to remove these organics are becoming important. Although biological treatment processes are very effective in removing organic material, they are not effective in removing small concentrations of organics.

The reason behind this is that the organic matters act as a nutrient source for most microorganisms and they cannot be expected to remove small concentrations of organics. In addition, these processes cannot be used to remove non-biodegradable organic substances which are commonly present in certain industrial wastewaters.

Chemical oxidation process using chlorine or ozone can also be used for removing this type of organics. Since they tend to leave oxidation by products which themselves may be unacceptable, adsorption technique remain as the best treatment method.

Adsorption is a surface phenomenon and effective adsorbents have a highly porous structure so that their surface area to volume ratio is very high. The solute molecule is held in contact with the adsorbent by a combination of physical, ionic and chemical forces.

When an adsorbent is left in contact with a solution the amount of adsorbed solute increases on the surface of the adsorbent and decreases in the solvent. When the number of molecules of solute is equal on the adsorbent and in the solvent it represents the adsorption equilibrium.

Generally the overall rate of adsorption is governed by the rate of diffusion of solute into the capillary pores of the adsorbent particle. The rate decreases with increasing particle size and increases with increasing solute concentration and temperature. Low molecular weight solutes are more easily adsorbed than the high molecular weight solutes.

 

 

 

 

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